31.
Match the compounds P-S with their carbonyl stretching frequencies (cm-1) I-VI in IR spectroscopy.
P. Acetone I. 1870
Q. Ethyl acetate II. 1800
R. Acetamide III. 1740
S. Acetyl chloride IV. 1700
V. 1660
VI. 1600

34.
In the reaction, \[P{h_3}P\xrightarrow{{\,\,{\text{Mel}}\,\,}}\left[ X \right]\xrightarrow{{n - {\text{BuLi}}}}\left[ Y \right]\]      the compounds X and Y, respectively, are

35.
The amino acid side chain high affinity for Ca2+ and Cu2+ in metallo-proteins is

37.
The two pericyclic reactions successively involved in the thermal transformation given below are
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