31. If an atom is in the 3d3 state, the angle between its orbital and spin angular momentum vectors ($$\overrightarrow {\bf{L}} $$ and $$\overrightarrow {\bf{S}} $$) is
32. Which one of the following statements is incorrect in vibrational spectroscopy with anharmonicity?
33. The pure rotational level of a molecule in the far-infrared region follows the formula F(J) = BJ(J + 1), where F(J) is the energy of the rotational level with quantum number J and B is the rotational constant. The lowest rotational energy gap in rotational Raman spectrum is
34. Caesium has a nuclear spin of 7/2. The hyperfine spectrum of the d lines of the caesium atom will consist of
35. The degeneracy of an excited state of nitrogen atom having electronic configuration 1s2 2s2 2p2 3d1 is
36. The population inversion in a two-level laser material cannot be achieved by optical pumping because
37. Group I lists some physical phenomena while Group II gives some physical parameters. Match the phenomenon with the corresponding parameter
Group I
Group II
P. Doppler broadening
1. Moment of inertia
Q. Natural broadening
2. Refractive index
R. Rotational spectrum
3. Lifetime of the energy level
S. Total internal reflection
4. Pressure
Group I | Group II |
P. Doppler broadening | 1. Moment of inertia |
Q. Natural broadening | 2. Refractive index |
R. Rotational spectrum | 3. Lifetime of the energy level |
S. Total internal reflection | 4. Pressure |