61. The vibrational spectrum of a molecule exhibits a strong line with P and R branches at a frequency $${\nu _1}$$ and a weaker line at a frequency $${\nu _2}$$ . The frequency $${\nu _3}$$ is not shown up. Its vibrational Raman spectrum shows a strongly polarized line at frequency $${\nu _3}$$ and no feature at $${\nu _1}$$ and $${\nu _2}$$ .
Which of the following statements is correct?
Which of the following statements is correct?
62. The short wavelength, cut-off of the continuous X-ray spectrum from a nickel target is 0.0825 nm. The voltage required to.be applied to an X-ray tube is
63. The allowed rotational energy levels of a rigid hetero-nuclear diatomic molecule are expressed as εJ = BJ (J + 1), where B is the rotational constant and J is a rotational quantum number.
In a system of such diatomic molecules of reduced mass μ, some of the atoms of one element are replaced by a heavier isotope, such that the reduced mass is changed to 1.05μ. In the rotational spectrum of the system, the shift in the spectral line, corresponding to a transition J = 4 → J = 5, is
In a system of such diatomic molecules of reduced mass μ, some of the atoms of one element are replaced by a heavier isotope, such that the reduced mass is changed to 1.05μ. In the rotational spectrum of the system, the shift in the spectral line, corresponding to a transition J = 4 → J = 5, is