43.
Melting point of a metal is 1356 K. When the liquid metal is undercooled to 1256 K, the free energy change for solidification, ΔGL-S = - 1000 J mol-1. On the other hand, if the liquid metal is undercooled to 1200 K, the free energy change (in J mol-1) for solidification is

46.
Decomposition of calcium carbonate occurs as:
CaCO3 = CaO + CO2 : ΔG0T = 17710 - 158T J. mol-1
What will be the decomposition temperature (in K) of CaCO3, if the activity of CaO is 0.5 and the pressure is 3 atmospheres?

47.
Roasting of a metallic sulfide MS in pure oxygen is carried out at a particular temperature where the probable stable solid phases are M, MS, MO and MSO4. In case the system attains equilibrium and thus satisfies phase rule, it is possible to obtain a combination of the following solid phases in the roasted product.
P. M, MS and MO
Q. M, MS, MO and MSO4
R. MSO4, MS and MO
S. MS and MO

48.
G = U + PV - TS. Then which one of the following is correct?

49.
In case of homogenous nucleation, the critical edge length for a cubed shaped nucleus is (Y : Energy per unit area of interface between the product and the parent phase; Δg : Gibbs free energy change per unit volume)

Read More Section(Metallurgical Thermodynamics and Kinetics)

Each Section contains maximum 100 MCQs question on Metallurgical Thermodynamics and Kinetics. To get more questions visit other sections.