A closed system is cooled reversibly from 100°C to 50°C. If no work is done on the system
A. Its internal energy (U) decreases and its entropy (S) increases
B. U and S both decreases
C. U decreases but S is constant
D. U is constant but S decreases
Answer: Option B
Solution(By Examveda Team)
Since here heat is taken from the system \[Q = - ve\]From second law of thermodynamics \[TdS \ge \delta Q\]
Since given reversible process \[TdS = \delta Q\]
$$ \Rightarrow dS = - ve$$
From first law of thermodynamics
$$\eqalign{ & \delta Q = dU \cr & \Rightarrow dU = - ve \cr} $$
Related Questions on Chemical Engineering Thermodynamics
A. Maxwell's equation
B. Thermodynamic equation of state
C. Equation of state
D. Redlich-Kwong equation of state
Henry's law is closely obeyed by a gas, when its __________ is extremely high.
A. Pressure
B. Solubility
C. Temperature
D. None of these
A. Enthalpy
B. Volume
C. Both A & B
D. Neither A nor B
Join The Discussion