31.
The absorption of [Co(NH3)6]2+ is

32.
The most suitable route to prepare the trans isomer of [PtCl2(NH3)(PPh3)] is

36.
In the reaction shown below, X and Y respectively are \[M{n_2}{\left( {CO} \right)_{10}}\xrightarrow{{\,\,\,Na\,\,\,}}\left( X \right)\xrightarrow{{C{H_3}CoCl}}\left( Y \right)\]

37.
The d-d absorption band of [Fe(H2O)6]2+ is split due to

39.
The structures of the complexes [Cu(NH3)4] (ClO4)2 and [Cu(NH3)4] (ClO4) in the solution respectively are