Examveda

A typical example of an exothermic reversible reaction conducted at high pressure in industry is

A. Dehydration of ethanol

B. Methanol synthesis

C. Reformation of methane

D. Polymerisation of ethylene

Answer: Option A


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Comments (2)

  1. Atanu Chatterjee
    Atanu Chatterjee:
    4 months ago

    The correct answer is:
    B. Methanol synthesis

    βœ… Explanation:
    Methanol synthesis:
    CO
    +
    2
    H
    2
    β‡Œ
    CH
    3
    OH
    Ξ”
    𝐻
    =
    βˆ’
    90.7
     
    kJ/mol
    CO+2H
    2
    ​
    β‡ŒCH
    3
    ​
    OHΞ”H=βˆ’90.7kJ/mol
    βœ”οΈ Exothermic: Releases heat

    βœ”οΈ Reversible: Can go both forward and backward

    βœ”οΈ High pressure: Conducted at 50–100 atm to favor the forward reaction (fewer gas moles on the product side)

    βœ”οΈ Industrial process using Cu/ZnO/Alβ‚‚O₃ catalyst at 200–300Β°C

    ❌ Incorrect Options:
    A. Dehydration of ethanol

    C
    2
    H
    5
    OH
    β†’
    C
    2
    H
    4
    +
    H
    2
    O
    C
    2
    ​
    H
    5
    ​
    OH→C
    2
    ​
    H
    4
    ​
    +H
    2
    ​
    O
    Endothermic and irreversible

    Requires high temperature, not high pressure

    C. Reformation of methane (Steam reforming)

    CH
    4
    +
    H
    2
    O
    β†’
    CO
    +
    3
    H
    2
    CH
    4
    ​
    +H
    2
    ​
    O→CO+3H
    2
    ​

    Highly endothermic

    Performed at high temperature, not necessarily high pressure

    D. Polymerisation of ethylene

    𝑛
    C
    2
    H
    4
    β†’
    (C
    2
    H
    4
    )
    𝑛
    nC
    2
    ​
    H
    4
    ​
    β†’(C
    2
    ​
    H
    4
    ​
    )
    n
    ​

    Exothermic but irreversible

    Conducted at high pressure, but not reversible

    βœ… Final Answer: B. Methanol synthesis

  2. Rajiv Giri
    Rajiv Giri:
    2 years ago

    Otlption B is right Answer, Pr-50-150 bar, Temp-250-300Β°C

Related Questions on Chemical Reaction Engineering

A first order gaseous phase reaction is catalysed by a non-porous solid. The kinetic rate constant and the external mass transfer co-efficients are k and $${{\text{k}}_{\text{g}}}$$ respectively. The effective rate constant (keff) is given by

A. $${{\text{k}}_{\text{e}}}{\text{ff}} = {\text{k}} + {{\text{k}}_{\text{g}}}$$

B. $${{\text{k}}_{\text{e}}}{\text{ff}} = \frac{{{\text{k}} + {{\text{k}}_{\text{g}}}}}{2}$$

C. $${{\text{k}}_{\text{e}}}{\text{ff}} = {\left( {{\text{k}}{{\text{k}}_{\text{g}}}} \right)^{\frac{1}{2}}}$$

D. $$\frac{1}{{{{\text{k}}_{\text{e}}}{\text{ff}}}} = \frac{1}{{\text{k}}} + \frac{1}{{{{\text{k}}_{\text{g}}}}}$$