A typical example of an exothermic reversible reaction conducted at high pressure in industry is
A. Dehydration of ethanol
B. Methanol synthesis
C. Reformation of methane
D. Polymerisation of ethylene
Answer: Option A
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A. $${{\text{k}}_{\text{e}}}{\text{ff}} = {\text{k}} + {{\text{k}}_{\text{g}}}$$
B. $${{\text{k}}_{\text{e}}}{\text{ff}} = \frac{{{\text{k}} + {{\text{k}}_{\text{g}}}}}{2}$$
C. $${{\text{k}}_{\text{e}}}{\text{ff}} = {\left( {{\text{k}}{{\text{k}}_{\text{g}}}} \right)^{\frac{1}{2}}}$$
D. $$\frac{1}{{{{\text{k}}_{\text{e}}}{\text{ff}}}} = \frac{1}{{\text{k}}} + \frac{1}{{{{\text{k}}_{\text{g}}}}}$$
The half life period of a first order reaction is given by (where, K = rate constant. )
A. 1.5 K
B. 2.5 K
C. $$\frac{{0.693}}{{\text{K}}}$$
D. 6.93 K
Catalyst is a substance, which __________ chemical reaction.
A. Increases the speed of a
B. Decreases the speed of a
C. Can either increase or decrease the speed of a
D. Alters the value of equilibrium constant in a reversible
A. $$ \propto {\text{CA}}$$
B. $$ \propto \frac{1}{{{\text{CA}}}}$$
C. Independent of temperature
D. None of these

The correct answer is:
B. Methanol synthesis
β Explanation:
Methanol synthesis:
CO
+
2
H
2
β
CH
3
OH
Ξ
π»
=
β
90.7
β
kJ/mol
CO+2H
2
β
βCH
3
β
OHΞH=β90.7kJ/mol
βοΈ Exothermic: Releases heat
βοΈ Reversible: Can go both forward and backward
βοΈ High pressure: Conducted at 50β100 atm to favor the forward reaction (fewer gas moles on the product side)
βοΈ Industrial process using Cu/ZnO/AlβOβ catalyst at 200β300Β°C
β Incorrect Options:
A. Dehydration of ethanol
C
2
H
5
OH
β
C
2
H
4
+
H
2
O
C
2
β
H
5
β
OHβC
2
β
H
4
β
+H
2
β
O
Endothermic and irreversible
Requires high temperature, not high pressure
C. Reformation of methane (Steam reforming)
CH
4
+
H
2
O
β
CO
+
3
H
2
CH
4
β
+H
2
β
OβCO+3H
2
β
Highly endothermic
Performed at high temperature, not necessarily high pressure
D. Polymerisation of ethylene
π
C
2
H
4
β
(C
2
H
4
)
π
nC
2
β
H
4
β
β(C
2
β
H
4
β
)
n
β
Exothermic but irreversible
Conducted at high pressure, but not reversible
β Final Answer: B. Methanol synthesis
Otlption B is right Answer, Pr-50-150 bar, Temp-250-300Β°C