42. In biological systems, the metal ions involved in electron transport are
43. The chromium (III) species formed soon after electron transfer between $$IrCl_6^{2 - }$$ and $$Cr\left( {{H_2}O} \right)_6^{2 + }$$ is
44. Structurally nickelocene is similar to ferrocene. Nickelocene attains stability due to the formation of
45. The complexes V(C6H6)2 and Cr(C6H6)2 are both readily oxidized in air to their respective cations. The number of unpaired electrons, respectively in each are
46. Zeise's salt is represented as
47. In the isoelectronic series, V$${\text{O}}_4^{3 - }$$, Cr$${\text{O}}_4^{2 - }$$ and Mn$${\text{O}}_4^ - $$, all members have intense charge transfer (CT) transitions. The incorrect statement is
48. The complex which obeys the 18-electron rule is
49. In photosynthesis, the predominant metal present in the reaction centre of photosystem II is
50. Consider the reactions:
1. [Cr(H2O)6]2+ + [CoCl(NH3)5]2+ → [Co(NH3)5(H2O)]2+ + [CrCl(H2O)5]2+
2. [Fe(CN)6]4- + [Mo(CN)8]3- → [Fe(CN)6]3- + [Mo(CN)8]4-
Which one of the following is the correct statement?
1. [Cr(H2O)6]2+ + [CoCl(NH3)5]2+ → [Co(NH3)5(H2O)]2+ + [CrCl(H2O)5]2+
2. [Fe(CN)6]4- + [Mo(CN)8]3- → [Fe(CN)6]3- + [Mo(CN)8]4-
Which one of the following is the correct statement?