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Logint1/2 = 0.693/K
so we have half time so by solving this equation calculate K which will be 0.05775 min^-1
now for first order irreversible equation the equation for calculating rate constant is
K = (1/T)*ln(CA0/CA)
CA = 0.25 and CA0 = 1
So by solving we will get t = 24 minutes
Thank you