In a liquid-liquid extraction, 10 kg of a solution containing 2 kg of solute C and 8 kg of solvent A is brought into contact with 10 kg of solvent B. Solvent A and B are completely immiscible in each other whereas solute C is soluble in both the solvents. The extraction process attains equilibrium. The equilibrium relationship between the two phases is Y* = 0.9X, where Y* is the kg of C/kg of B and X is kg of C/kg of A. Choose the correct answer.
A. The entire amount of C is transferred to solvent B
B. Less than 2 kg but more than 1 kg of C is transferred to solvent B
C. Less than 1 kg of C is transferred to B
D. No amount of C is tranferred to B
Answer: Option A
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We are given:
Initial solution: 10 kg containing
Solute C: 2 kg
Solvent A: 8 kg
Contacted with: 10 kg of solvent B
A and B are immiscible
Solute C is distributable between A and B
Equilibrium relationship:
š
ā
=
0.9
š
Y
ā
=0.9X
where:
š
=
kgĀ C
kgĀ A
X=
kgĀ A
kgĀ C
ā
š
ā
=
kgĀ C
kgĀ B
Y
ā
=
kgĀ B
kgĀ C
ā
Let:
š¶
š“
C
A
ā
: kg of C remaining in solvent A
š¶
šµ
C
B
ā
: kg of C extracted to solvent B
Total C =
š¶
š“
+
š¶
šµ
=
2
ā
kg
C
A
ā
+C
B
ā
=2kg
Also:
š
=
š¶
š“
8
X=
8
C
A
ā
ā
š
ā
=
š¶
šµ
10
Y
ā
=
10
C
B
ā
ā
From the equilibrium relationship:
š¶
šµ
10
=
0.9
ā
š¶
š“
8
10
C
B
ā
ā
=0.9ā
8
C
A
ā
ā
š¶
šµ
=
0.9
ā
10
8
ā
š¶
š“
=
1.125
ā
š¶
š“
C
B
ā
=0.9ā
8
10
ā
ā C
A
ā
=1.125ā C
A
ā
Substitute into mass balance:
š¶
š“
+
š¶
šµ
=
2
ā
š¶
š“
+
1.125
ā
š¶
š“
=
2
ā
2.125
ā
š¶
š“
=
2
ā
š¶
š“
=
2
2.125
ā
0.9412
ā
kg
C
A
ā
+C
B
ā
=2āC
A
ā
+1.125ā C
A
ā
=2ā2.125ā C
A
ā
=2āC
A
ā
=
2.125
2
ā
ā0.9412kg
Then:
š¶
šµ
=
2
ā
0.9412
=
1.0588
ā
kg
C
B
ā
=2ā0.9412=1.0588kg
ā Final Answer:
B. Less than 2 kg but more than 1 kg of C is transferred to solvent B
We are given:
Initial solution: 10 kg containing
Solute C: 2 kg
Solvent A: 8 kg
Contacted with: 10 kg of solvent B
A and B are immiscible
Solute C is distributable between A and B
Equilibrium relationship:
š
ā
=
0.9
š
Y
ā
=0.9X
where:
š
=
kgĀ C
kgĀ A
X=
kgĀ A
kgĀ C
ā
š
ā
=
kgĀ C
kgĀ B
Y
ā
=
kgĀ B
kgĀ C
ā
Let:
š¶
š“
C
A
ā
: kg of C remaining in solvent A
š¶
šµ
C
B
ā
: kg of C extracted to solvent B
Total C =
š¶
š“
+
š¶
šµ
=
2
ā
kg
C
A
ā
+C
B
ā
=2kg
Also:
š
=
š¶
š“
8
X=
8
C
A
ā
ā
š
ā
=
š¶
šµ
10
Y
ā
=
10
C
B
ā
ā
From the equilibrium relationship:
š¶
šµ
10
=
0.9
ā
š¶
š“
8
10
C
B
ā
ā
=0.9ā
8
C
A
ā
ā
š¶
šµ
=
0.9
ā
10
8
ā
š¶
š“
=
1.125
ā
š¶
š“
C
B
ā
=0.9ā
8
10
ā
ā C
A
ā
=1.125ā C
A
ā
Substitute into mass balance:
š¶
š“
+
š¶
šµ
=
2
ā
š¶
š“
+
1.125
ā
š¶
š“
=
2
ā
2.125
ā
š¶
š“
=
2
ā
š¶
š“
=
2
2.125
ā
0.9412
ā
kg
C
A
ā
+C
B
ā
=2āC
A
ā
+1.125ā C
A
ā
=2ā2.125ā C
A
ā
=2āC
A
ā
=
2.125
2
ā
ā0.9412kg
Then:
š¶
šµ
=
2
ā
0.9412
=
1.0588
ā
kg
C
B
ā
=2ā0.9412=1.0588kg
ā Final Answer:
B. Less than 2 kg but more than 1 kg of C is transferred to solvent B
Less than 2 kg but more than 1 kg of C is transferred to solvent B
could you show the solution for this
How di you find the answer can you show you solution
Answer is 1.0588 kg of solute is transferred.