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LoginB. Methanol synthesis
β Explanation:
Methanol synthesis:
CO
+
2
H
2
β
CH
3
OH
Ξ
π»
=
β
90.7
β
kJ/mol
CO+2H
2
β
βCH
3
β
OHΞH=β90.7kJ/mol
βοΈ Exothermic: Releases heat
βοΈ Reversible: Can go both forward and backward
βοΈ High pressure: Conducted at 50β100 atm to favor the forward reaction (fewer gas moles on the product side)
βοΈ Industrial process using Cu/ZnO/AlβOβ catalyst at 200β300Β°C
β Incorrect Options:
A. Dehydration of ethanol
C
2
H
5
OH
β
C
2
H
4
+
H
2
O
C
2
β
H
5
β
OHβC
2
β
H
4
β
+H
2
β
O
Endothermic and irreversible
Requires high temperature, not high pressure
C. Reformation of methane (Steam reforming)
CH
4
+
H
2
O
β
CO
+
3
H
2
CH
4
β
+H
2
β
OβCO+3H
2
β
Highly endothermic
Performed at high temperature, not necessarily high pressure
D. Polymerisation of ethylene
π
C
2
H
4
β
(C
2
H
4
)
π
nC
2
β
H
4
β
β(C
2
β
H
4
β
)
n
β
Exothermic but irreversible
Conducted at high pressure, but not reversible
β Final Answer: B. Methanol synthesis