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71
The energy balance equation over a tubular reactor under transient conditions is
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Answer & Solution
Answer: Option D
Solution:
In chemical reaction engineering, the energy balance for a tubular reactor under transient (unsteady-state) conditions involves time-dependent and position-dependent variables such as temperature and concentration.

This results in a balance that includes both time and spatial derivatives, making it a partial differential equation (PDE).

Due to the presence of temperature-dependent properties (like reaction rate constants, heat capacities, and heat generation terms), the equation typically contains non-linear terms.

Therefore, the energy balance under these conditions is expressed as a non-linear partial differential equation.

Option A: An ordinary non-linear differential equation is incorrect because it doesn't account for spatial variation.

Option B: An algebraic differential equation is incorrect because the energy balance is not algebraic — it involves derivatives.

Option C: A linear partial differential equation is incorrect because the equation is usually non-linear due to reaction kinetics and temperature dependencies.

Correct answer: A non-linear partial differential equation.
72
Brunaur, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates is not used to derive BET equation?
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Answer & Solution
Answer: Option B
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73
A space velocity of 5 hr-1 means that
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Answer: Option A
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74
An isothermal irreversible reaction is being carried out in an ideal tubular flow reactor. The conversion in this case will __________ with decrease in space time.
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Answer: Option C
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75
For multiple reactions, the flow pattern within the vessel affects the
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Answer: Option C
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76
If helium is introduced in a reactor containing O2, SO2 and SO3 at equilibrium, so that total pressure increases while volume and temperature remains constant. In this case the dissociation of SO3 (as per Le Chatlier principle)
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Answer & Solution
Answer: Option A
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77
The temperature dependence of reaction rate constant (K) by Arhenius law is given by
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Answer: Option A
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78
Consider the nth order irreversible liquid phase reaction A → B. Which one of the following plots involving half life of the reaction $$\left( {{{\text{t}}_{\frac{1}{2}}}} \right)$$  and the initial reactant concentration (CA0) gives a straight line plot?
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Answer: Option C
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79
For a tubular flow reactor with uniform concentration and temperature, the independent variable is
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Answer: Option B
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80
A chemical reaction, A → 3B, is conducted in a constant pressure vessel. Starting with pure A, the volume of the reaction mixture increases 3 times in 6 minutes. The fractional conversion is
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Answer & Solution
Answer: Option C
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