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Petroleum Refinery Engineering
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Pick out the wrong statement.

Answer & Solution
Correct Answer: Option C
The rate of decomposition of olefins in catalytic cracking is actually faster than in thermal cracking. This is because catalytic cracking provides a more efficient pathway with lower activation energy compared to thermal cracking. Catalysts accelerate the cracking process, leading to a higher rate of reaction for olefins.

Option A is incorrect because n-paraffins generally crack faster than iso-paraffins due to less stable intermediates.

Option B is correct as stated; catalytic cracking is indeed endothermic, requiring heat input, whereas the regeneration of the catalyst is exothermic, releasing heat.

Option D cannot be the answer since one of the previous statements is incorrect.
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2 Comments
Rituraj Baruah
Rituraj Baruah 2 years ago
C. In catalytic cracking olefins crack 1000-10000 times faster than thermal process.

With reference to the book " Elements of petroleum refinery engineering" by OP Gupta. Chapter "Thermal and catalytic cracking".
Debasish Gogoi
Debasish Gogoi 6 years ago
Catalytic cracking is an endothermic process but hydrocracking is an exothermic process.
So its definately not (B)