Answer & Solution
Answer: Option
A
Solution:
Option A: Always the same irrespective of the reaction
This option suggests that the half-life period of a first-order reaction is always the same regardless of the reaction. This statement is correct. For a first-order reaction, the half-life period (t₁/₂) is constant and does not depend on the initial concentration of the reactants.
Option B: Dependent on initial concentration of the reactants
This option suggests that the half-life period of a first-order reaction depends on the initial concentration of the reactants. This statement is incorrect. The half-life of a first-order reaction is independent of the initial concentration and remains constant throughout the reaction.
Option C: Proportional to the initial concentration of reactants
This option suggests that the half-life period of a first-order reaction is proportional to the initial concentration of the reactants. This statement is incorrect. In a first-order reaction, the half-life is not proportional to the initial concentration; it remains constant regardless of the concentration.
Option D: Half the specific rate constant
This option suggests that the half-life period of a first-order reaction is half the specific rate constant. This statement is incorrect. The half-life of a first-order reaction is related to the rate constant (k) by the formula t₁/₂ = 0.693/k. It is not half the rate constant but rather a function of the rate constant.
Conclusion:
The correct answer is Option A: Always the same irrespective of the reaction because, for a first-order reaction, the half-life period is constant and does not depend on the initial concentration of the reactants.